Alicia Keys, Nelly, Rob Thomas, Shakira, Billy Idol and The Arcade Fire are also set to appear, according to the Conde Nast Media Group.

CBS will air a two-hour “Fashion Rocks” special on September 9 (9 p.m. EST). The announcement said it will be the last televised appearance of Destiny’s Child, who have announced plans to disband after their tour ends.

New York Fashion Week will run September 9-16. Stefani will close the week with her L.A.M.B. designer show.